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Effect of Gas Dilution on PEM Fuel Cell Performance and Impedance Response

Identifieur interne : 001294 ( Main/Exploration ); précédent : 001293; suivant : 001295

Effect of Gas Dilution on PEM Fuel Cell Performance and Impedance Response

Auteurs : M. Boillot [France] ; C. Bonnet [France] ; N. Jatroudakis [France] ; P. Carre [France] ; S. Didierjean [France] ; François Lapicque [France]

Source :

RBID : ISTEX:AD70974E8B37E1726C491F4E46447164BF91741E

Descripteurs français

English descriptors

Abstract

In this work, an experimental study of gas dilution on the performance of a polymer electrolyte membrane (PEM) fuel cell was carried out. Impedance spectra were analysed depending on the dilution of either hydrogen or oxygen by nitrogen. By comparison of the impedance spectra obtained, the three loops were attributed to hydrogen oxidation, oxygen reduction and a low frequency diffusion process. Hydrogen oxidation was shown to be more complicated when the anode side was fed by a simulated reforming gas than with the same dilution rate with nitrogen.

Url:
DOI: 10.1002/fuce.200500101


Affiliations:


Links toward previous steps (curation, corpus...)


Le document en format XML

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<term>Anode side</term>
<term>Capacitance</term>
<term>Carbon dioxide</term>
<term>Carbon monoxide</term>
<term>Cathode side</term>
<term>Cell temperature</term>
<term>Cell voltage</term>
<term>Characteristic frequency</term>
<term>Charge transfer resistance</term>
<term>Charge transfer resistance rcta</term>
<term>Constant phase element</term>
<term>Current density</term>
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<term>Diffusion layer thickness</term>
<term>Dilution</term>
<term>Dilution rate</term>
<term>Dilution rates</term>
<term>Electroanalytical chemistry</term>
<term>Electrochemical society</term>
<term>Electrochimica</term>
<term>Electrochimica acta</term>
<term>Equivalent circuit</term>
<term>Experimental data</term>
<term>Flow meters</term>
<term>Flow rate</term>
<term>Frequency loop</term>
<term>Fuel cell</term>
<term>Fuel cell performance</term>
<term>Fuel cells</term>
<term>Good agreement</term>
<term>High frequencies</term>
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<term>Humidification conditions</term>
<term>Humidification temperatures</term>
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<term>Imaginary part</term>
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<term>Impedance response</term>
<term>Impedance spectra</term>
<term>Impedance spectroscopy</term>
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<term>Medium frequency loops</term>
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<term>Original research paper</term>
<term>Original research paper boillot</term>
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<term>Power sources</term>
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<term>Pure hydrogen</term>
<term>Pure oxygen</term>
<term>Real part</term>
<term>Reference electrode</term>
<term>Relative humidity</term>
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<term>Tafel slope</term>
<term>Verlag gmbh</term>
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<term>Carbon dioxide</term>
<term>Carbon monoxide</term>
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<term>Cell voltage</term>
<term>Characteristic frequency</term>
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<term>Charge transfer resistance rcta</term>
<term>Constant phase element</term>
<term>Current density</term>
<term>Diffusion coefficient</term>
<term>Diffusion layer thickness</term>
<term>Dilution</term>
<term>Dilution rate</term>
<term>Dilution rates</term>
<term>Electroanalytical chemistry</term>
<term>Electrochemical society</term>
<term>Electrochimica</term>
<term>Electrochimica acta</term>
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<term>Impedance</term>
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<term>Original research paper</term>
<term>Original research paper boillot</term>
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<term>Oxygen dilution</term>
<term>Oxygen reduction</term>
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<term>Power sources</term>
<term>Pseudo capacitance</term>
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<front>
<div type="abstract" xml:lang="en">In this work, an experimental study of gas dilution on the performance of a polymer electrolyte membrane (PEM) fuel cell was carried out. Impedance spectra were analysed depending on the dilution of either hydrogen or oxygen by nitrogen. By comparison of the impedance spectra obtained, the three loops were attributed to hydrogen oxidation, oxygen reduction and a low frequency diffusion process. Hydrogen oxidation was shown to be more complicated when the anode side was fed by a simulated reforming gas than with the same dilution rate with nitrogen.</div>
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